{4-Bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ3 S,N,O}(triphenylphosphane-κP)nickel(II)
نویسندگان
چکیده
The Ni(II) atom in the title complex, [Ni(C(13)H(8)BrNOS)(C(18)H(15)P)], is coordinated by the N, O and S atoms of the dianionic tridentate ligand, and its square-planar geometry is completed by a phosphane P atom. The dihedral angle between the aromatic rings in the 4-bromo-2-[(2-sulfido-phen-yl)imino-meth-yl]phenolate ligand is 2.01 (14)°. The most prominent feature of the packing is the presence of supra-molecular chains aligned along the a axis, mediated by C-H⋯S inter-actions.
منابع مشابه
(6-Hydroxy-2-{[2-(N-methylcarbamothiolyl)hydrazin-1-ylidene-κ2 N 1,S]methyl}phenolato-κO 1)(triphenylphosphane-κP)nickel(II) chloride
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